Tiny mineral inclusions picture the chemical exchange between Earth's mantle and atmosphere

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Tiny mineral inclusions picture the chemical exchange between Earth's mantle and atmosphere
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Using synchrotron techniques, scientists have unveiled important information on The Great Oxidation Event by studying apatite inclusions in zircon crystals from old magmas.

Using synchrotron techniques, scientists have unveiled important information on The Great Oxidation Event by studying apatite inclusions in zircon crystals from old magmas with the ESRF -- Extremely Brilliant Source. The results are published inAround 2.4 billion years ago, a pivotal moment in Earth's history took place: The Great Oxidation Event. During this period, a significant amount of oxygen accumulated in the atmosphere.

Scientists have long tried to study the interaction between atmosphere and the Earth's mantle. The mission is already complicated to be accomplished in the modern Earth, and even more so in the early Earth, when the atmosphere and plate tectonics were changing at rapid rates.

Moreira and colleagues decided to explore inclusions of phosphate-mineral apatite in zircon grains that are crystallized in magmas formed in an ancient subduction zone, and measured their sulphur valence speciation using X-ray absorption near edge structure at the ESRF, the brightest synchrotron light source.

The experiment results show that apatite inclusions in zircons from magmas that crystallised prior to the Great Oxidation Event have a relatively reduced sulphur redox state, whereas after the Great Oxidation Event they are more oxidised. The analysis on zircon shows that these magmas shared a similar source and that the younger samples had incorporated a sediment component.

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