Synthesis and characterization of a near-infrared persistent luminescent Cr-doped zinc gallate–calcium phosphate composite

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Synthesis and characterization of a near-infrared persistent luminescent Cr-doped zinc gallate–calcium phosphate composite
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New glow-in-the-dark material can track path of drugs through the humanbody

, CZGO) is a representative NIR-emitting PersL material. On the other hand, amorphous calcium phosphate is a widely used drug carrier due to its high biocompatibility. In this work, we present a design of an ACP-based drug carrier with PersL properties, by forming a CZGO–ACP composite.

The PersL properties of CZGO were preserved by composite formation, while it is found that the Zncould migrate from CZGO to ACP during composite formation, leading to different luminescence mechanisms between pure CZGO and the CZGO–ACP composite. The electronic structure of the composite was analyzed by synchrotron X-ray absorption spectroscopy, and a structure–luminescence correlation was proposed.

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