Physicists discover new rule for orbital formation in chemicalreactions NatureComms
f. Following the standard classification, we should therefore more correctly refer to this state as an interface resonance.
In the present case of oligophenyls on the Cu surface, the distinct momentum structure of the hybridising molecular orbital, as well as the existence of gaps in the surface-projected bulk band structure of the metal, allowed us to detect and trace in minute detail how hybrid orbitals are formed between the metal’s bulk states and the lowest unoccupied molecular orbital that becomes partially occupied in the process.
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